Product ID:47989, TCLP BSE NEUTRAL DICHLOROBENZENE (SUPP DATA)
MSDS Date:09/27/1993
FSC:6630
NIIN:00N066611
MSDS Number: CBDSW

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

BENZENE, HEXACHLORO-; (HEXACHLOROBENZENE) (SARA 313)

CAS: 118-74-1

RTECS: DA2975000

Fraction By Weight: 0.1%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ETHANE, HEXACHLORO-; (HEXACHLOROETHANE) (SARA 313) (CERCLA)

CAS: 67-72-1

RTECS: KI4025000

Fraction By Weight: 0.1%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 1 PPM, A2

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

BENZENE, P-DICHLORO-; (P-DICHLOROBENZENE) (SARA 313)

CAS: 106-46-7

RTECS: CZ4550000

Fraction By Weight: 0.1%

OSHA PEL 75 PPM

ACGIH TLV: 10 PPM, A3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

TOLUENE, 2,4-DINITRO-; (2,4-DINITROTOLUENE) (SARA 313)

CAS: 121-14-2

RTECS: XT1575000

Fraction By Weight: 0.1%

OSHA PEL S, 1.5 MG/,M3

ACGIH TLV: 0.15 MG/M3, A2

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

1,3-BUTADIENE, HEXACHLORO-; (HEXACHLOROBUTADIENE) (SARA

CAS: 87-68-3

RTECS: EJ0700000

Fraction By Weight: 0.1%

OSHA PEL 0.02 PPM

ACGIH TLV: S, 0.02 PPM, A2

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

BENZENE, NITRO-; (NITROBENZENE) (SARA 302/313)

CAS: 98-95-3

RTECS: DA6475000

Fraction By Weight: 0.1%

OSHA PEL S, 1 PPM

ACGIH TLV: S, 1 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ACETONE; (2-PROPANONE) (SARA 313) (CERCLA)

CAS: 67-64-1

RTECS: AL3150000

Fraction By Weight: 99-100%

OSHA PEL 1000 PPM

ACGIH TLV: 750 PPM/1000 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

891 MG/KG

CAS: 110-86-1

RTECS: UR8400000

Fraction By Weight: 0.1%

OSHA PEL 5 PPM

ACGIH TLV: 5 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

IARC

RTECS: 9999999ZZ

ANTICIPATED TO BE

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:BURNS EYES, IRRITATES RESPIRATORY
TRACT, CONTAINS MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. LOW BLOOD PRESSURE (HYPOTENSION). IRRITATES SKIN,
DERMATITIS, IRRITATES NOSE AND THROAT, HEADACHE, DIZZINESS,
GASTROINTESTINAL DISTURBANCES, DEPRESSES CENTRAL NERVOUS SYSTEM,
CONVULSIONS, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:P-DICHLOROBENZENE:IARC MONOGRAPHS, SUPP,
VOL 7, PG 192, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS.
1994:ANTIC (ING 9)
Effects of Overexposure:HLTH HAZS:NARCOSIS, COMA, LIVER DAMAGE, KIDNEY
DAMAGE, REPORTED ANIMAL CARCINOGEN. CARCINOGENICITY:INDEFINITE IN
MAN. RESPIRATORY FAILURE, ERYTHEMA, ECZEMA, CONJUNCTIVITIS, AND
CORNEAL EROSION. MAY CA USE CORNEAL INJURY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR @ LST 15 MIN. CONT MD. SKIN:PROMPTLY
WASH W/MILD SOAP & LG VOLS OF WATER. REMOVE CONTAM CLTHG.
INHAL:IMMED MOVE TO FRESH AIR. GIVE OXYG IF BRTHG IS LABORED. IF
BRTHG STOPS, GIVE ARTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING
BY MOUTH TO AN UNCON PERSON. NEVER TRY TO MAKE UNCON PERSON VOMIT.
GIVE LG AMTS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO INDUCE
VOMIT. GIVE (SUPDAT)

Flash Point Method:CC
Flash Point:-2F,-19C
Lower Limits:2.6%
Upper Limits:13.%
Extinguishing Media:DRY CHEMICAL, ALCOHOL FOAM. WATER MAY BE
INEFFECTIVE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPS FOR EXPLO MIX W/AIR. CNTNRS MAY
EXPLODE UNDER FIRE CNDTNS. FOLLOWING TOX VAPS ARE FORMED WHEN MATL
IS HEATED TO DECOMP. OXIDES, OF NITROGEN, (SUPP DATA)

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINERS. KEEP
AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR NIOSH/MSHA APPROVED SELF CONTAINED
BREATHING APPARATUS.
Ventilation:USE ONLY IN EXHAUST HOOD.
Protective Gloves:WEAR BUTYL RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE/PART NO:1X1ML, ACET 1000U. EXPLO HAZS:HYDROGEN CHLORIDE,
CYANIDE. MATLS TO AVOID:HALOGENS, ALDEHYDES, AMMONIA & CHLORINATED
CMPDS. FIRST AID PROC:SYRUP OF IPECAC. IMMEDIATELY CONTACT A PHYSI
CIAN.

Boiling Pt:B.P. Text:133F,56C
Melt/Freeze Pt:M.P/F.P Text:-139F,-95C
Vapor Pres:181 @ 20C
Vapor Density:2
Spec Gravity:0.792 (H*2O=1)
Evaporation Rate & Reference:14.4 (BUTYL ACETATE=1)
Solubility in Water:100
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:1

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG BASES, OXIDIZING AGENTS, AMINES, OXYG, FLUORINE,
CHLORINE & BROMINE. ALKANOLAMINES, (SUPP DATA)
Hazardous Decomposition Products:OXIDES OF NITROGEN, HYDROGEN CHLORIDE,
CYANIDE.

Waste Disposal Methods:COMPLY WITH ALL FEDERAL, STATE OR LOCAL
REGULATIONS. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTIED. EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES:HANDLE AS IF
THEY WERE FULL.

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expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
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particular situation.